The Stereochemistry of Epoxidation of 5β-methyl-19-norsteroidal 9,10-alkenes-Reference-Cited by-同舟云学术

The Stereochemistry of Epoxidation of 5β-methyl-19-norsteroidal 9,10-alkenes

Published:2005-04 Issue:4 Volume:2005 Page:236-237
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Uyanik Cavit¹,Malay Aslihan¹,Hanson James R.²,Hitchcock Peter B.²,Yildirim Kudret³

Affiliation:

1. Department of Chemistry, University of Kocaeli, Izmit 41300, Kocaeli, Turkey

2. Department of Chemistry, University of Sussex, Brighton, Sussex, BN1 9QJ, UK

3. Department of Chemistry, University of Sakarya, Mithatpasa 54100, Sakarya, Turkey

Abstract

Crystallographic studies have shown that the oxidation of 3β,6β-dihydroxy-5β-methyl-19-norsteroidal 9(10)-alkenes with chromium trioxide leads to 9α,10α-epoxides as minor products.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/0308234054213519

Reference10 articles.

1. Transition-metal-catalyzed epoxidations

2. Encyclopedia of Reagents for Organic Synthesis, ed. PaquetteL.A., John Wiley and Sons, Chichester, 1995, p. 1273.

3. 5β,6β-Epoxidation of 3β-Cholesteryl Acetate and its Analogues

4. 627. Steroids and related compounds. Part VII. Some derivatives of 5-methyl-10-norandrost-8(9)-ene-3 : 6-diol-17-one

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