An Efficient and Practical Procedure for Preparation of Gem-Diacetates from Aldehydes Catalysed by Magnesium Perchlorate-Reference-Cited by-同舟云学术

An Efficient and Practical Procedure for Preparation of Gem-Diacetates from Aldehydes Catalysed by Magnesium Perchlorate

Published:2006-03 Issue:3 Volume:2006 Page:199-202
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Yang Shu-Tao¹

Affiliation:

1. The College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, P. R. China

Abstract

A mild and efficient method for the preparation of gem-diacetates from aldehydes with acetic anhydride is described using a catalytic amount of magnesium perchlorate giving excellent yields under solvent-free conditions.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823406776330648

Reference60 articles.

1. Reinvestigation of the Mechanism ofgem-Diacylation: Chemoselective Conversion of Aldehydes to Variousgem-Diacylates and Their Cleavage under Acidic and Basic Conditions

2. Protecting groups in organic synthesis. Part 8. Conversion of aldehydes into geminal diacetates

3. Montmorillonite clay catalysis V1: An efficient and facile procedure for deprotection of 1,1-diacetates

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