Zinc/Ammonium Formate: A New Facile System for the Rapid and Selective Reduction of Oximes to Amines

Author:

Abiraj K.1,Gowda D. Channe1

Affiliation:

1. Department of Studies in Chemistry, University of Mysore, Mysore-570 006, India

Abstract

Various oximes, both aldoximes and ketoximes, are selectively reduced to corresponding amines employing low cost zinc dust and ammonium formate despite presence of other functional groups such as halogens, –OH, –OCH3, –COOH, –CN, > C = C < and –CH3.

Publisher

SAGE Publications

Subject

General Chemistry

Reference17 articles.

1. HutchinsR.O., and HutchinsM. K., Comprehensive Organic Synthesis Vol. 8; eds. FlemingI., Pergamon press; Oxford, 1991; pp. 60.

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3. Synthese d'aziridines secondaires cis disubstituees

4. Actinobolin via the anomeric effect

5. MarchJ., Advanced Organic Chemistry, 4th edn. A Wiley-Interscience Publication, Singapore, 1992; pp. 1219.

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