[Tetra(n-butyl)ammonium] [di(μ-bromo) bis{dichloro(p-tolyl)antimonate(III)}]: Synthesis and crystal structure-Reference-Cited by-同舟云学术

[Tetra(n-butyl)ammonium] [di(μ-bromo) bis{dichloro(p-tolyl)antimonate(III)}]: Synthesis and crystal structure

Published:2000-04 Issue:4 Volume:2000 Page:198-199
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Singh Ajai K.¹,Amburosea C.V.,Jha N. K.¹,Sharma P.²,Cabrera A.²,E-Perz G.²

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, New Delhi 110 016, India

2. Instituto de Quimica, UNAM, Circuito Exterior, Coyoacan, D.F. 04510, Mexico

Abstract

The crystal structure of a salt of mixed trihalo(aryl)antimonate(III) anion, [ n-Bu4N]2[( p-tol)Cl2Sb(μ-Br)2SbCl2( p-tol)] ( p-tol = p-tolyl) reveals that the anion is dimeric in nature and two Sb atoms of the dimer are asymmetrically bridged by bromide ions (Sb-Br(bridging) = 2.985(2) / 3.373(1) Å).

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823400103166959

Reference9 articles.

1. Phenylchloroantimon(III)ates; their preparations, and the crystal structures of Me4N[PhSbCl3], [Hpy]2[PhSbCl4], and Me4N[Ph2SbCl2]

2. Synthesis of (p-TolSb)n by reaction of Cp2Co with p-TolSbCl2, crystal structure of [Cp2Co][p-TolSbCl3], and electroreduction of p-TolSbCl2

3. Synthesis of (Me3SiCH2Sb)n and reactions with ditellurides: crystal structure of [Cp2Co][Me3SiCH2SbCl3]

4. CRYSTAL STRUCTURES OF Bu4[PhSbBr2Cl] AND Bu4N[Ph2SbBr2]

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