Reductive Cleavage of the Se–Se Bond in the Presence of a Zn/AlCl3 System: Synthesis of Selenol Esters

Author:

Movassagh Barahman1,Shamsipoor Mojgan1,Joshaghani Mohammad2

Affiliation:

1. Department of Chemistry, K.N. Toosi University of Technology, PO Box 15875-4416, Tehran Iran

2. Department of Chemistry, Razi University, 67149 Kermanshah, Iran

Abstract

Selenol esters were prepared in good yields by reacting diselenides with carboxylic acid anhydrides in dry acetonitrile in the presence of a Zn/AlCl3 system.

Publisher

SAGE Publications

Subject

General Chemistry

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Organoselenium Chemistry;Encyclopedia of Inorganic and Bioinorganic Chemistry;2018-12-12

2. Electron Capture Dissociation of Disulfide, Sulfur–Selenium, and Diselenide Bound Peptides;Journal of the American Society for Mass Spectrometry;2012-09-20

3. Nucleophilic Selenium;Organoselenium Chemistry;2011-11-14

4. Electron Attachment to Diselenides Revisited: Se–Se Bond Cleavage Is Neither Adiabatic nor the Most Favorable Process;Journal of Chemical Theory and Computation;2011-05-24

5. Highly Efficient One-Step Conversion of Selenol Esters into Symmetrical Diselenides in the Presence of Elemental Iodine in Methanolic Solution;Phosphorus, Sulfur, and Silicon and the Related Elements;2009-12-28

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