Kinetic control of the aquation of the Hexathiocyanatochromate(Iii) Ion by Associative interaction of Poly(Acrylamide) in Aqueous Medium-Reference-Cited by-同舟云学术

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Kinetic control of the aquation of the Hexathiocyanatochromate(Iii) Ion by Associative interaction of Poly(Acrylamide) in Aqueous Medium

Published:2003-01 Issue:1 Volume:2003 Page:8-9
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Anbalagan Krishnamoorthy¹,Sutharson Subramanian¹

Affiliation:

1. Department of Chemistry, Gandhigram Rural Institute (Deemed University), Gandhigram 624 302, India

Abstract

Cooperative interaction of poly(acrylamide) is found to decelerate significantly the aquation rate of [Cr(NCS)6]3- in acidic, neutral, and basic media, which is an indication of kinetic control of macromolecules on reactions.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823403103172940

Reference6 articles.

1. Control of the Thermal and Photochemical Aquation of the Hexacyanochromate(III) and Aquapentacyanochromate(III) Ions by Formation of a Supramolecular Structure with [32]ane-N8

2. Preferential solvation in kinetics. III. Thermal and photochemical solvolysis of Reinecke's ion in acetonitrile-water mixtures

3. Fluorescence quenching and electron transfer in poly(methacrylic acid) with covalently bound anthracenes

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