Synthesis and crystal structures of two new (Te, N,) type hybrid organotellurium ligands-Reference-Cited by-同舟云学术

Synthesis and crystal structures of two new (Te, N,) type hybrid organotellurium ligands

Published:2001-08 Issue:8 Volume:2001 Page:339-341
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Singh Ajai K.¹,Sooriyakumar J.¹,Kadarkaraisamy M.¹,Drake J.E.²,Hursthouse M.B.³,Light M.E.³,Butcher R.J.⁴

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, New Delhi 110016, India

2. Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario N9B 3P4, Canada

3. Department of Chemistry, University of Southampton, Southampton SO17 1BJ, UK

4. Department of Chemistry, Howard University, Washington, D.C. 20059, USA

Abstract

The reaction of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te 2, has resulted in N-[2-(4-methoxyphenyltelluro)ethyl] benzamide (L1) and N-[2-(4-methoxyphenyl telluro)propyl] phthalimide (L2) respectively, which are potentially (Te, N)-type ligands. Their NMR (1H and 13C) spectra are characteristic and single crystal structures are solved. The Te-C(alkyl) distance [2.140(8)/2.151(4) Å] is longer than Te-C(aryl) distance [2.107(8)/2.128(5) Å].

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823401103169991

Reference27 articles.

1. Recent developments in the ligand chemistry of tellurium

2. Hybrid (Te, O) ligands 2- (phenyltelluromethyl)tetrahydro-2H-pyran (L1) and 2-(2-{4-methoxyphenyl} telluorethyl)- 1,3-dioxane (L2), and their palladium(II) and platinum(II) complexes

3. Synthesis and spectra of novel diorganotellurides and diorganoditellurides. Potential polydentate hybrid organotellurium ligands

4. N-[2-(4-Methoxyphenyltelluro)ethyl]phthalimide: Synthesis and complexation with palladium(II)

5. N-[2-(4-methoxyphenyltelluro)ethyl]phthalimide (L1): synthesis, oxidation by ruthenium(III) chloride and ligation with ruthenium(II). Crystal structures of L1, its oxidized product and of [RuCl2(p-cymene)·L1]

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3. Secondary bonding in functionalized organotellurium compounds: preparation and structural characterization of bis(acetamido)tellurium(IV) diiodide and bis(4-methylbenzoylmethyl)tellurium(II);Journal of Organometallic Chemistry;2005-01

4. N-[2-(4-Methoxyphenyltelluro)ethyl]benzamide (L1) and N-[2-(4-methoxyphenyl telluro)propyl]phthalimide (L2): synthesis and ligation with palladium(II), platinum(II) and ruthenium(II). Crystal structures of L1 and L2, the latter as a mixed crystal with L2H2;Polyhedron;2002-03

5. Chapter 6.3 Six-membered ring systems: Triazines, tetrazines and fused ring polyaza systems;A Critical Review of the 2001 Literature Preceded by Two Chapter on Current Heterocyclic Topics;2002