Electrical conductivities of manganate-permanganate mixtures: New mixed-valence manganate(VI)–(VII) salts Ba3(MnO4)4 and BaK(MnO4)2-Reference-Cited by-同舟云学术

Electrical conductivities of manganate-permanganate mixtures: New mixed-valence manganate(VI)–(VII) salts Ba3(MnO4)4 and BaK(MnO4)2

Published:2000-03 Issue:3 Volume:2000 Page:116-117
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Rosseinsky David R.¹,Muthakia Gerald K.¹

Affiliation:

1. School of Chemistry, The University, Exeter EX4 4QD, UK

Abstract

Mixed-valent salts Ba3(MnO4)4 and BaK(MnO4)2 are indicated by maximal 1:1 mixed-component conductivities, as governed by Marcus reorganisation energies.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823400103166823

Reference12 articles.

1. Single-crystal mixed-valent tripotassium manganate(VI)/(VII). X-ray diffraction structure and electron-transfer rate by dielectric relaxometry and DC conductimetry

2. Dielectric Relaxometry — Manganate(VI)–(VII) in Solid and Solution States

3. Site-transfer electronic conductivity. The hopping or polaron (direct-current) mechanism from dielectric relaxation studies on intervalence mixtures and charge-transfer adducts

4. Electron transfer in solids. Temperature dependence of dielectric relaxation and conductivity in mixed-valence potassium manganate–permanganate

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