Affiliation:
1. Abteilung für Lehramtskandidaten der Chemie, Fachbereich Chemie, Pharmazie und Geowissenschaften, Johannes Gutenberg –Universität, Mainz 55128, Germany
Abstract
2-Mono- and 2,9-di-substituted 1,10-phenanthrolines with 4-pyridine units attached either via 1,4-phenylene- or 4-ethynyl-phenyl spacers, have been synthesised. The strategy is based on the introduction of 4-trimethylsilylphenyl group(s) at the phenanthroline core with the subsequent ipso-substitution of TMS groups by bromine or iodine and successive Suzuki or Sonogashira reactions with 4-pyridineboronic acid or 4-ethynylpyridine, respectively.
Cited by
4 articles.
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1. Synthesis, X-ray Diffraction and Computational Druglikeness Evaluation of New Pyrrolo[1,2-a][1,10]Phenanthrolines Bearing a 9-Cyano Group;Symmetry;2024-07-17
2. Fifty Shades of Phenanthroline: Synthesis Strategies to Functionalize 1,10-Phenanthroline in All Positions;Chemical Reviews;2024-05-15
3. Diastereoselective Synthesis and X-ray Structure of New Stable Dicyano (8aRS,10SR,11SR)-9,9-dicyano-10-aryl-11-benzoyl -8a,9,10,11-tetrahydropyrrolo[1,2-a][1,10]phenanthrolines;Journal of Chemical Research;2011-06
4. Columnar supramolecular architecture of crystals of 2-(4-Iodophenyl)-1,10-phenanthroline derived from values of intermolecular interaction energy;CrystEngComm;2011