Dicobaltbisnorbornadienetetracarbonyl [Co2(Nbd)2(CO)4] Reacts with Oxygen-Containing Alkynes and Gives Crossover Products in the Presence of other Alkenes-Reference-Cited by-同舟云学术

Dicobaltbisnorbornadienetetracarbonyl [Co2(Nbd)2(CO)4] Reacts with Oxygen-Containing Alkynes and Gives Crossover Products in the Presence of other Alkenes

Published:2008-09 Issue:9 Volume:2008 Page:516-519
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Coogan Michael P.¹,Wilkins Derek S.¹

Affiliation:

1. Department of Chemistry, Cardiff University, Cardiff, CF10 3AT, Cymru/Wales, UK

Abstract

Dicobaltbisnorbornadienetetracarbonyl, [Co2(nbd)2(CO)4] DDTC, (nbd = norbornadiene) which has previously been reported to be unreactive with alkynes is shown to react with oxygen-containing alkynes; in the presence of other alkenes crossover reaction is seen which has important implications for the mechanism of this, and possibly other, reactions.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X349718

Reference16 articles.

1. Organocobalt complexes. Part II. Reaction of acetylenehexacarbonyldicobalt complexes, (R1C2R2)Co2(CO)6, with norbornene and its derivatives

2. (2-3:5-6-η-Norbornadiene)propylidyneheptacarbonyltricobalt, containing the Co3C tetrahedral cluster

3. 120. Some diolefincobalt carbonyl complexes

4. The Pauson–Khand Reaction: the Catalytic Age Is Here!

5. Heterobimetallic alkyne complexes in organic synthesis: An asymmetric variant of the Pauson-Khand reaction

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Atropisomerisation in sterically hindered α,β-disubstituted cyclopentenones derived from an intermolecular cobalt(0)-mediated Pauson–Khand reaction;Organic & Biomolecular Chemistry;2010

2. ChemInform Abstract: Dicobaltbisnorbornadienetetracarbonyl [Co2(nbd)2(CO)4] Reacts with Oxygen-Containing Alkynes and Gives Crossover Products in the Presence of Other Alkenes.;ChemInform;2009-02-10