Microwave Activation of Alumina and its use as a Catalyst in Synthetic Reactions-Reference-Cited by-同舟云学术

Microwave Activation of Alumina and its use as a Catalyst in Synthetic Reactions

Published:2009-02 Issue:2 Volume:2009 Page:120-123
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Dadush Eric¹,Green James F.¹,Sease Aaron²,Naravane Abhijit¹,Pagni Richard M.¹,Kabalka George W.¹

Affiliation:

1. Departments of Chemistry and Radiology, University of Tennessee, Knoxville, TN 37996, USA

2. Virginia Union University, VA 23220, USA

Abstract

Microwave irradiation is a simple and efficient method of activating gamma alumina. Alumina activated in this manner is an excellent medium in which to carry out the Diels–Alder reaction and, in conjunction with additional microwave irradiation, the Claisen rearrangement. Several 2-allylphenols formed in the Claisen rearrangement rapidly undergo ring closure on alumina to form dihydrobenzofurans demonstrating the Brønsted acidity of the solid.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X401790

Reference33 articles.

1. Infrared and Gravimetric Study of the Surface Hydration of γ-Alumina

2. Catalytic Aluminas: Surface Models and Characterization of Surface Sites

3. Organic reactions on alumina

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