One-Pot, Nickel triflate-catalysed homocoupling of aryl chlorides in the Presence of Metallic Magnesium-Reference-Cited by-同舟云学术

One-Pot, Nickel triflate-catalysed homocoupling of aryl chlorides in the Presence of Metallic Magnesium

Published:2009-06 Issue:6 Volume:2009 Page:397-399
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Lv Dan¹,Zhang Yan-Yan¹,Li Jing-Hua¹

Affiliation:

1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, 310032, P. R. China

Abstract

The homocoupling reaction of aryl chlorides was successfully performed in one-pot without preparation of a Grignard reagent in advance. Various aryl chlorides underwent homocoupling reactions affording the corresponding symmetrical biaryls in moderate to good yields. The nickel triflate catalyst was recovered easily and reused smoothly with only a little loss of its activity.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X460759

Reference21 articles.

1. Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes

2. Activation of Grignard reagents by transition-metal complexes. A new and simple synthesis of trans-stilbenes and polyphenyls

3. Discovery of the cross-coupling reaction between Grignard reagents and C(sp2) halides catalyzed by nickel–phosphine complexes

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