Kinetics and Activation Thermodynamics of the Solvolysis of Tert-Pentyl and Tert-Hexyl Halides in Alcohols-Reference-Cited by-同舟云学术

Kinetics and Activation Thermodynamics of the Solvolysis of Tert-Pentyl and Tert-Hexyl Halides in Alcohols

Published:2002-11 Issue:11 Volume:2002 Page:535-536
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Albuquerque Lídia C.¹,Moita Luísa C.¹,Gonçalves Raquel C.¹,Macedo Eugénia A.²

Affiliation:

1. Centro de Electroquímica e Cinética da Universidade de Lisboa (CECUL), Departamento de Química e Bioquímica, Faculdade de Ciências da Universidade de Lisboa, Campo Grande, Edifício C8, 1749-016 Lisboa, Portugal

2. Laboratório de Processos de Separação Reacção (LSRE), Departamento de Engenharia Química, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal

Abstract

The influences of solvent and substrate were interpreted through the values of rate constants and infinite dilution activity coefficients obtained for the solutes 2-chloro- and 2-bromo-2-methylbutane and 3-chloro-3-methylpentane in several monohydric alcohols at 298.15 K.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823402103170907

Reference11 articles.

1. Kinetic and thermodynamic study of 2-bromo-2-methylbutane, 2-chloro-2-methylbutane and 3-chloro-3-methylpentane in diols

2. Infinite Dilution Activity Coefficients Predicted from UNIFAC Model. New Experimental Data for the Solvolytic Reactions of 2-Chloro-2-methylpropane in Methanol/Ethanol, Methanol/2-Methoxyethanol, and Ethanol/2-Methoxyethanol

3. Infinite Dilution Activity Coefficients from UNIFAC Model for 2-Chloro-2-methylpropane in Binary Mixtures of Alcohols. Application to the Mechanistic Study of Solvolytic Reactions

4. Study of initial- and transition-state solvation in the solvolysis oftert-butyl halides in alcohols from infinite dilution activity coefficients

5. Study of initial state and transition state solvation in the Menschutkin reaction of triethylamine with ethyl iodide in alcohols from infinite dilution activity coefficients

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