Synthesis of terminal arylacetylenes by a Stille coupling reaction catalysed by a MCM-41-supported bidentate phosphine palladium(O) complex-Reference-Cited by-同舟云学术

Synthesis of terminal arylacetylenes by a Stille coupling reaction catalysed by a MCM-41-supported bidentate phosphine palladium(O) complex

Published:2008-11 Issue:11 Volume:2008 Page:615-618
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Hao Wenyan¹,Wang Yue¹,Sheng Shouri¹,Cai Mingzhong¹

Affiliation:

1. Department of Chemistry, Jiangxi Normal University, Nanchang 330022, P.R. China

Abstract

A variety of terminal arylacetylenes have been conveniently synthesised in good to high yields by Stille coupling of aryl halides with ethynyltributylstannane catalysed by a MCM-41-supported bidentate phosphine palladium(O) complex in an aqueous medium and under air. Our system not only avoids the requirement for water-free and oxygen-free conditions, but also solves the basic problem of palladium catalyst reuse.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X360328

Reference56 articles.

1. A convenient synthesis of 1-bromoolefins and acetylenes by a chain extension of aldehydes

2. A Convenient Synthesis of Ethynyl-N-heteroarenes

3. Highly Efficient and Selective Procedures for the Synthesis of γ-Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E

4. One-pot approach for the regioselective synthesis of β-keto sulfones based on acid-catalyzed reaction of sulfonyl chlorides with arylacetylenes and water

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