A Controlled and Selective Bromination of Phenols by Benzyltriphenylphosphonium Tribromide-Reference-Cited by-同舟云学术

A Controlled and Selective Bromination of Phenols by Benzyltriphenylphosphonium Tribromide

Published:2002-06 Issue:6 Volume:2002 Page:272-275
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Hajipour Abdol Reza¹,Mallakpour Shadpour E.¹,Imanieh Hossein²,Pourmousavi Seied Ali¹

Affiliation:

1. Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan, 84156, IR, Iran

2. Department of Chemistry, Faculty of Science, Imam Khomaini International University, Ghazvin, 288, IR. Iran

Abstract

Reactions of phenols with benzyltriphenylphosphonium tribromide in dichloromethane–methanol mixture (2:1) gave mono, di and tri brominated phenols at room temperature with high selectivity and good yields.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823402103171951

Reference27 articles.

1. (a) FusonR.C., Reaction of Organic Compounds, New York, Wiley, 1962, 58, 98

2. NormanR.O.C., and TaylorR., Electrophilic Substitution in Benzenoid Compounds, New York, American Elsevier, 1965, 130.

3. An environmentally benign synthesis of organic ammonium tribromides (OATB) and bromination of selected organic substrates by tetrabutylammonium tribromide (TBATB)

4. The Brominating Properties of Tetramethylammonium Tribromide1a

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