Stereoselective Synthesis of Difunctionalised 1,3-dienes Containing Silicon and Sulfur via Palladium Catalysed Cross-Coupling Reactions-Reference-Cited by-同舟云学术

Stereoselective Synthesis of Difunctionalised 1,3-dienes Containing Silicon and Sulfur via Palladium Catalysed Cross-Coupling Reactions

Published:2008-06 Issue:6 Volume:2008 Page:305-307
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Zhang Haiyun¹,Ye Xinglin²,Cai Mingzhong¹

Affiliation:

1. Department of Chemistry, Jiangxi Normal University, Nanchang 330027, P. R. China

2. Department of Chemistry, Jiujiang College, Jiujiang 332000, P. R. China

Abstract

Hydromagnesiation of alkynylsilanes 1 in diethyl ether gave ( Z)-α-silylvinyl Grignard reagents 2, which underwent a cross-coupling reaction with ( E)-α-iodovinyl sulfides 3 in the presence of Pd(PPh3)4 as catalyst to afford stereoselectively ( Z,Z)-2-silyl-3-arylsulfanyl-substituted 1,3-dienes 4 in good yields.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X320656

Reference35 articles.

1. Stereospecific synthesis of olefins through sequential cross-coupling reactions

2. Selenium in Organic Synthesis: A Novel Route to 1-Phenylselenobutadienes and 1,4-Dicarbonyl Compounds

3. Nickel and palladium catalysed coupling of vinyl selenides with trimethylsilylmethylmagnesium chloride : A new synthesis of allyl silanes

4. Stereoselective synthesis of (E,E)-1-arylselenobutadienes by cross-coupling reactions in the presence of palladium catalyst

5. Novel stereoselective synthesis of 1,3-dienyl selenides by palladium–copper cocatalyzed cross coupling reactions of (E)-α-selanylvinylstannanes

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