Zn(OTf)2.6H2O catalysed acylation of aldehydes: Preparation of 1,1-diacetates and α-chloroalkyl esters-Reference-Cited by-同舟云学术

Zn(OTf)2.6H2O catalysed acylation of aldehydes: Preparation of 1,1-diacetates and α-chloroalkyl esters

Published:2005-02 Issue:2 Volume:2005 Page:88-90
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Su Weike¹,Can Jin¹

Affiliation:

1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, P.R. China

Abstract

1,1-Diacetates (acylals) and α-chloroalkyl esters were prepared from carbonyl compounds with acylating reagents in the presence of 5% mol hexaaqua zinc triflate [Zn(OTf)2.6H2O] with good yields under mild reaction conditions.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/0308234054497065

Reference32 articles.

1. Protecting groups in organic synthesis. Part 8. Conversion of aldehydes into geminal diacetates

2. A Synthetic Precursor of Verrucarin A

3. An efficient synthesis of diacetates from aldehydes using beta zeolite

4. Ueber Thiele's Xylol‐Oxydation und über Terephtalaldehydgrün

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