A facile stereoselective synthesis of 1,3-dienyl and 1,4-dienyl sulfides by hydrostannylation-Stille tandem reaction of acetylenic sulfides-Reference-Cited by-同舟云学术

A facile stereoselective synthesis of 1,3-dienyl and 1,4-dienyl sulfides by hydrostannylation-Stille tandem reaction of acetylenic sulfides

Published:2009-09 Issue:9 Volume:2009 Page:558-561
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Yao Fang¹²,Hao Wenyan¹,Cai Mingzhong¹

Affiliation:

1. Department of Chemistry, Jiangxi Normal University, Nanchang 330022, P. R. China

2. Department of Chemistry and Pharmaceutical Engineering, West Branch of Zhejiang University of Technology, Quzhou 324000, P. R. China

Abstract

1,3-Dienyl and 1,4-dienyl sulfides can be stereoselectively synthesised in one pot under mild conditions in good yields by the palladium-catalysed hydrostannylation of acetylenic sulfides, followed by Stille coupling with alkenyl or allylic halides, respectively.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X12506792542828

Reference59 articles.

1. A facile and highly stereoselective synthesis of (2E)-, (2E,4E)-unsaturated amides and related natural products

2. Highly Stereoselective Synthesis of (1E)-2-Methyl-1,3-dienes by Palladium-Catalyzedtrans-Selective Cross-Coupling of 1,1-Dibromo-1-alkenes with Alkenylzinc Reagents

3. The Wittig reaction: comments on the mechanism and application as a tool in the synthesis of conjugated dienes

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