Raney Ni–Al alloy-mediated reduction of benzils in water-Reference-Cited by-同舟云学术

Raney Ni–Al alloy-mediated reduction of benzils in water

Published:2009-09 Issue:9 Volume:2009 Page:579-581
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Liu Guo-Bin¹,Zhao Hong-Yun¹,Dai Lu¹,Thiemann Thies²,Tashiro Hideki³,Tashiro Masashi⁴

Affiliation:

1. Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, P.R. China

2. Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6–1, Kasuga-koh-en, Kasuga, Fukuoka 816-8580, Japan

3. Department of Bioscience Development, School of Bioresources, Hiroshima Prefectural University, 562 Nanatsuka-cho, Shobara City, Hiroshima 727-0023, Japan

4. National Institute of Advanced Industrial Science and Technology AIST Central 5, 1–1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

Abstract

Raney Ni–AI alloy in a dilute aqueous alkaline solution has been shown to be a powerful reducing agent and is highly effective for the reduction of alkylbenzils and alkoxybenzils to afford the corresponding 1,2-diarylethers at 90°C, in the absence of organic solvents. 4,4′-Dinitrobenzil was transformed selectively to 1,2-bis(4-aminophenyl)-ethane.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823409X12506792542783

Reference19 articles.

1. Reductions of Benzil

2. The Wolff-Kishner Reaction of Hydrazones

3. Reduction of unsymmetrical benzils using sodium dithionite

4. THE REDUCTION OF PARA-DIMETHYLAMINOBENZIL1

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