Determination and Structural Correlation of PkA Values of P-Substituted Trans-β-Aroylacrylic Acids

Author:

Pfendt Lidija1,Popović Gordana2,Kostić Milka3,Stevović Ljubomir3,Drakulić Branko3,Juranić Ivan1

Affiliation:

1. Faculty of Chemistry, University of Belgrade, PO Box 158, 11000 Belgrade, Yugoslavia

2. Faculty of Pharmacy, University of Belgrade, PO Box 146, 11000 Belgrade, Yugoslavia

3. Center for Chemistry, IChTM Belgrade, 11000 Belgrade, Yugoslavia

Abstract

For a series of 10 p-substituted trans-β-aroylacrylic acids, pKa values were determined spectrophotometrically in water at 25°C and at ionic strength 0.1 M (NaCl). The thermodynamic pKa values were correlated with Hammett σp constants.

Publisher

SAGE Publications

Subject

General Chemistry

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