Highly selective Friede–Crafts monoacylation of ferrocene catalysed by ytterbium(III) triflate

Author:

Su Weike1,Li Jianjun1

Affiliation:

1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou, 310014, P.R. China

Abstract

In the presence of a catalytic amount of ytterbium(III) triflate[Yb(OTf)3], ferrocene reacted with anhydrides or acyl chlorides to afford monoacylferrocenes in high yields under moderate conditions. An efficient, simple and environmentlly friendly procedure was provided. The catalyst was easily recovered and reused without any loss of activity.

Publisher

SAGE Publications

Subject

General Chemistry

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Zeolites for preparation of acylferrocenes;From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference, Proceedings of the 15th International Zeolite Conference;2007

2. Titanium Dioxide‐Mediated Friedel–Crafts Acylation of Aromatic Compounds in Solvent‐Free Condition under Microwave Irradiation;Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry;2006-05-01

3. Copper Triflate–Catalyzed Cross‐Aldol Condensation: A Facile Synthesis of α,α′‐Bis(Substituted Benzylidene) Cycloalkanones;Synthetic Communications;2005-12

4. Highly Selective Friedel?Crafts Monoacylation of Ferrocene Catalyzed by Ytterbium(III) Triflate.;ChemInform;2005-02-15

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