Clean-Chemistry Sulfonation of Aromatics-Reference-Cited by-同舟云学术

Clean-Chemistry Sulfonation of Aromatics

Published:2002-07 Issue:7 Volume:2002 Page:326-327
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Corby Brian W.¹,Gray Anthony D.¹,Meaney Padraig J.¹,Falvey Michael J.¹,Lawrence Gregory P.¹,Smyth Timothy P.¹

Affiliation:

1. Department of Chemical and Environmental Sciences, University of Limerick, National Technological Park, County Limerick, Ireland

Abstract

A solution of TFAA/H2SO4 is an atom-efficient liquid-phase system for rapid sulfonation of aromatic structures; H2SO4 is consumed stoichiometrically and the spent trifluoroacetic anhydride (TFAA) is readily recovered as trifluoroacetic acid (TFA) which can be recycled to TFAA.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823402103172329

Reference9 articles.

1. Benzenesulfonic Acids and Their Derivatives

2. On developing cleaner organic unit processes

3. Toward a Clean Alternative to Friedel−Crafts Acylation: In Situ Formation, Observation, and Reaction of an Acyl Bis(trifluoroacetyl)phosphate and Related Structures

4. Industrially Viable Alternative to the Friedel−Crafts Acylation Reaction: Tamoxifen Case Study

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