Sixty Years of the Grunwald–Winstein Equation: Development and Recent Applications-Reference-Cited by-同舟云学术

Sixty Years of the Grunwald–Winstein Equation: Development and Recent Applications

Published:2008-02 Issue:2 Volume:2008 Page:61-66
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Kevill Dennis N.¹,D'Souza Malcolm J.²

Affiliation:

1. Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois, 60115-2862, USA

2. Department of Chemistry, Wesley College, 120 N. State Street, Dover, Delaware 19901-3875, USA

Abstract

The development of scales of values for solvent nucleophilicity and for the aromatic-ring parameter are described. These are applied to solvolytic addition to carbocations and, together with improved solvent ionising power scales, to solvolyses proceeding with a 1,2-aryl shift and to solvolytic displacements at acyl carbon and at a heteroatom, such as phosphorus or sulfur.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X293189

Reference115 articles.

1. The Correlation of Solvolysis Rates

2. The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories

3. WellsP.R., Linear free energy relationships, Academic Press, New York, 1962. p. 67.

4. Nucleophilicity and ionizing power in binary solvent mixtures

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