NMR Study of the Naphtho-1,3-dithioles Formed from Carbamodithioates and 2,3-dichloro-1,4-naphthoquinone

Author:

Aly Ashraf A.1,Brown Alan B.2,El-Shaieb Kamal M.1,Hassan Alaa A.1,Bedair Tarek M. I.1

Affiliation:

1. Department of Chemistry, Faculty of Science, El-Minia University, 61519-El-Minia, Egypt

2. Chemistry Department, Florida Institute of Technology, 150 W University Blvd, Melbourne, Florida 32901, USA

Abstract

Reaction of triethylammonium 1,2-ethanediylbis(carbamodithioate) with 2,3-dichloro-1,4-naphthoquinone in DMF furnished N,N'-ethylenebis(2-iminonaphtho[2,3- d][1,3]dithiole-4,9-dione) in 94% yield. Triethylammonium N-arylcarbamodithioates reacted with 2,3-dichloro-1,4-naphthoquinone to give 2-( N-arylimino)naphtho[2,3- d][1,3] dithiole-4,9-diones in good yields. NMR spectroscopic data of the products are discussed.

Publisher

SAGE Publications

Subject

General Chemistry

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