Bis (Salicylaldehyde-1, 2-Phenylene Diimine)Mn(III) Chloride (Mn(III)-Salophen) Catalysed Oxidation of Thiols to Symmetrical Disulfides Using Urea Hydrogen Peroxide (UHP) as Mild and Efficient Oxidant

Author:

Karami Bahador1,Montazerozohori Morteza1,Habibi Mohammad Hossein2

Affiliation:

1. Department of Chemistry, Yasouj University, Yasouj 75914-353, Iran

2. Department of Chemistry, Isfahan University, Isfahan 81745-117, Iran

Abstract

A variety of thiols were oxidised efficiently by a catalytic amount of Mn(III)-salophen 1 in the presence of urea hydrogen peroxide adduct 2 as a convenient and mild oxidant to afford the corresponding disulfides in high yields in quite short reaction times.

Publisher

SAGE Publications

Subject

General Chemistry

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