New functionalised C,C-bipyrazoles. Synthesis and cation binding properties

Author:

Attayibat Ahmed1,Radi Smaail1,Lekchiri Yahya2,Ramdani Abdelkrim1,Hacht Brahim3,Morcellet Michel4,Bacquet Maryse4,Willai Stéphanie4

Affiliation:

1. Département de Chimie, Faculté des Sciences, Université Med I, 60 000 Oujda, Morocco

2. Département de Biologie, Faculté des Sciences, Université Med I, 60 000 Oujda, Morocco

3. Laboratoire de Spéciation et de Surveillance de la Pollution en Méditerranée, Département de Chimie, Faculté des Sciences, Université Med I, 60 000 Oujda, Morocco

4. Laboratoire de Chimie Macromoléculaire, Université des Sciences et Technologies de Lille, 59655 Villeneuve d'Ascq, France

Abstract

The synthesis of two new C,C-bipyrazoles ligands with a side-arm bearing a functionalised donor-group is reported. The complexation properties of these compounds towards bivalent metal ions (Hg2+, Cd2+, Pb2+, Cu2+, Zn2+) and alkaline metal ions (Li+, Na+, K+) was studied by a liquid–liquid extraction process and the extracted cation percentage was determined by atomic absorption measurements.

Publisher

SAGE Publications

Subject

General Chemistry

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