Synthesis and photoreactions of polymethyl substituted [2.2]metacyclophanes-Reference-Cited by-同舟云学术

Synthesis and photoreactions of polymethyl substituted [2.2]metacyclophanes

Published:2008-11 Issue:11 Volume:2008 Page:650-654
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Paudel Arjun¹,Shimizu Tomoe¹,Yamato Takehiko¹

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga 840-8502, Japan

Abstract

Photo-oxygenation of 4,5,6,8,12,13,14,16-octamethyl[2.2]metacyclophane using a high-pressure mercury lamp produced a mixture of mono- and bis-endoperoxides in quantitative yield, while irradiation with sunlight in chloroform afforded 1,2,3,6,7,8-hexamethyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene in 20% yield.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X375089

Reference24 articles.

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