Comparative Evaluation of Oxidising and Nucleophilic Properties of Some α-Nucleophiles-Reference-Cited by-同舟云学术

Comparative Evaluation of Oxidising and Nucleophilic Properties of Some α-Nucleophiles

Published:2002-07 Issue:7 Volume:2002 Page:336-338
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Cassagne Thierry¹,Cristau Henri-Jean¹,Delmas Gérard²,Desgranges Michel²,Lion Claude³,Magnaud Gilbert²,Torreilles Έliane¹,Virieux David¹

Affiliation:

1. Laboratoire de Chimie Organique ENSCM, UMR 5076 du CNRS, 8, rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France

2. Centre d'Έtudes du Bouchet, Ministère de la Défense, BP n° 3, 91710 Vert-le-petit, France

3. Institut de Topologie et de Dynamique des Systèmes de I'Université Paris 7, Upresa 7086, 1, rue Guy de la Brosse, 75005 Paris, France

Abstract

Six α-nucleophiles were evaluated at pH = 8 in an aqueous methanolic solution for their oxidising power towards tetrahydrothiophene, and the nucleophilic properties towards paraoxon. MMPP and m-CPBA are the most versatile reagents and can act as nucleophiles as well as oxidising agents.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823402103172194

Reference12 articles.

1. NOUVEAUX DECONTAMINANTS. DESTRUCTION DE TOXIQUES ORGANOPHOSPHORES ET SOUFRES PAR L'ACIDE MONOPEROXYPHOSPHORIQUE

2. Peroxyhydrolysis of nerve agent VX and model compounds and related nucleophilic reactions

3. Oxidative detoxification of phosphonothiolates

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