Attempted synthesis of 1-pheny-1, 2-cyclohexadiene and Wurtz-like condensation products in the reaction of 1-(2,3-dibromocyclohex-1-en-1-yl) benzene with zinc-Reference-Cited by-同舟云学术

Attempted synthesis of 1-pheny-1, 2-cyclohexadiene and Wurtz-like condensation products in the reaction of 1-(2,3-dibromocyclohex-1-en-1-yl) benzene with zinc

Published:2001-09 Issue:9 Volume:2001 Page:368-369
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Ceylan Mustafa¹,Budak Yakup¹

Affiliation:

1. Department of Chemistry, Faculty of Arts and Sciences, Gaziosmanpaşa University, 60250 Tokat, Türkïye

Abstract

The thermal rearrangement of 8 at 150 °C and 180 °C gave 9 and 10, respectively. The reaction of 1-(2,3-dibromocyclohex-1-en-1-yl)benzene 9 with activated zinc gave Wurtz-like dimeric products 3 and 4 instead of expected allene 2.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823401103170304

Reference25 articles.

1. Polarized nonvertical excited states: FORS MCSCF and CI study of torsion and bending in allene

2. Small-ring cyclic cumulenes: theoretical studies of the structure and barrier to inversion in cyclic allenes

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