Reactions of Carbonyl Compounds in Basic Solutions. Part 351: The Alkaline Hydrolysis and Reactivity – Structure – Spectra Correlations of (Z)-4-(Substituted Benzylidene)-2-Phenyl-4H-Oxazol-5-Ones-Reference-Cited by-同舟云学术

Reactions of Carbonyl Compounds in Basic Solutions. Part 351: The Alkaline Hydrolysis and Reactivity – Structure – Spectra Correlations of (Z)-4-(Substituted Benzylidene)-2-Phenyl-4H-Oxazol-5-Ones

Published:2002-07 Issue:7 Volume:2002 Page:309-310
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Bowden Keith¹,Perjéssy Alexander²,Benko Ján²,Fabian Walter M. F.³,Kolehmainen Erkki⁴,Melikian Gauguik S.⁵,Hritzová Ol'ga⁶,Laihia Katri⁴,Vollárová Ol'ga²,Taupuzian Vigen O.⁷,Kiriakossian Nelli⁷,Nissinen Maija⁴

Affiliation:

1. Department of Biological and Chemical Sciences, University of Essex, Colchester, Essex CO4 3SQ, UK

2. Department of Organic Chemistry and Department of Physical Chemistry, Faculty of Natural Sciences, Comenius University, SK - 842 15 Bratislava, Slovak Republic

3. Institute of Chemistry, Karl Franzens University Graz, A - 8010 Graz, Austria

4. Department of Chemistry, University of Jyväskylä, FIN – 40351 Jyväskylä, Finland

5. Institute of Organic Chemistry, Yerevan State University, ARM – 375049 Yerevan, Armenia

6. Department of Organic Chemistry, Faculty of Natural Sciences, P. J. Šafárik University, SK – 04167 Košice, Slovak Republic

7. Insitute of Fine Organic Chemistry, NAS Republic of Armenia, ARM – 375014 Yerevan, Armenia

Abstract

The kinetics of the alkaline hydrolysis and the configuration, conformation and electronic structure were studied using IR, NMR spectroscopy, X-ray analysis and AM1 theoretical calculations for a series of (Z)-4-(substituted benzylidene)-2-phenyl-4H-oxazol-5-ones (1) and compared with analogous results reported for (E)-4-benzylidene-2-phenyl-4H-furan-5-ones (5) and related compounds.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823402103172266

Reference7 articles.

1. Reactions of Carbonyl Compounds in Basic Solutions. Part 34. The Mechanism of the Base-Catalysed Ring Fission of 2,3-Diphenylcycloprop-2-en-1-one

2. Base-catalysed hydrolysis of ?-lactones: reactivity-structure correlations for 3-(aryl- and alkylmethylene)-(Z)-1(3H)-isobenzofuranones

3. Base-catalysed hydrolysis of ?-lactones: reactivity-structure correlations for 3-(substituted phenoxy- and thiophenoxymethylene)-(Z )-1(3H )-isobenzofuranones

4. Spectral properties and kinetics of the alkaline hydrolysis of chromium, tricarbonyl[3-[(η6-aryl)methylene]-Z-1(3H)-isobenzofuranones]

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