Poly(vinylpyrrolidone)-bromine Complex; a Mild and Efficient Reagent for Selective Bromination of Alkenes and Oxidation of Alcohols-Reference-Cited by-同舟云学术

Poly(vinylpyrrolidone)-bromine Complex; a Mild and Efficient Reagent for Selective Bromination of Alkenes and Oxidation of Alcohols

Published:2005-08 Issue:8 Volume:2005 Page:481-483
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Lakouraj Moslem Mansour¹,Tajbakhsh Mahmood¹,Mokhtary Masoud¹

Affiliation:

1. Department of Chemistry, Mazandaran University, Babolsar, 47415, Iran

Abstract

Poly(vinylpyrrolidone)-bromine complex (PVP–Br2) is easily prepared and used as a mild and convenient reagent for selective bromination of alkenes and at the position α-hydrogen of active carbonyl compounds. Selective oxidation of benzylic alcohols in the presence of aliphatic alcohols were also achieved at room temperature.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823405774663246

Reference33 articles.

1. A simple, safe, and easy bromination of alkene using TBABr3: An organic laboratory experiment

2. A mild and efficient sonochemical bromination of alkenes using tetrabutylammonium tribromide

3. Pyrrolidone hydrotribromide: a brominating agent with selectivity for ketones

4. Halogenation with copper(II) halides. Halogenation of olefins with complexed copper(II) halides

5. Manganese-mediated novel dibromination of olefins with tetradecyltrimethylammonium permanganate and trimethylbromosilane

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