Unusual product from the reaction of 2-diazo-1-[5-(4-methoxybenzoyl)-2,3-dihydropyrrolizin-1-yl]ethanone with rhodium (II) acetate-Reference-Cited by-同舟云学术

Unusual product from the reaction of 2-diazo-1-[5-(4-methoxybenzoyl)-2,3-dihydropyrrolizin-1-yl]ethanone with rhodium (II) acetate

Published:2007-11 Issue:11 Volume:2007 Page:670-672
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Cuevas-Yañez Erick¹,Hernández-Ortega Simón²,Fuentes-Benites Aydeé¹,González-Romero Carlos¹,Cruz-Almanza Raymundo²

Affiliation:

1. Departamento de Química Orgánica, Facultad de Química, Universidad Autónoma del Estado de México. Paseo Colón esq. Paseo Tollocan, 50120, Toluca, Mexico

2. Instituto de Química, UNAM. Circuito Exterior, Ciudad Universitaria, Coyoacán, 05419, México, D.F.

Abstract

The rhodium(II)-catalysed reaction of the diazoketone derived from 5-(4-methoxybenzoyl)-2,3-dihydropyrrolizin-1-carboxylic acid (anirolac) did not give the expected intramolecular cyclisation product but afforded the 2,3-dihydropyrrolizin-1-one only an elimination product. X-ray studies confirmed the structure.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823407X268944

Reference11 articles.

1. Rh2(OAc)4-Catalyzed Regioselective Intermolecular C-H Insertion Reactions: Novel Synthesis of 2-Pyrrol-3′-yloxindoles

2. Synthesis of a Ketorolac ModelviaAromatic Carbenoid Insertion

3. Intramolecular Carbenoid Insertions: the Reactions of α-Diazoketones Derived from Pyrrolyl and Indolyl Carboxylic Acids with Rhodium(II) Acetate

4. Rhodium(II) catalyzed intramolecular insertion of carbenoids derived from 2-pyrrolyl and 3-indolyl α-diazo-β-ketoesters and α-diazoketones

5. Ab initio study of the molecular structure and photoelectron spectra of azatriquinane, triazatricyclodecane and tricyclodecane

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. ChemInform Abstract: Unusual Product from the Reaction of 2-Diazo-1-[5-(4-methoxybenzoyl)-2,3-dihydropyrrolizin-1-yl]ethanone with Rhodium (II) Acetate.;ChemInform;2008-05-20