An Unusual Ozonolysis of the Δ8(14)-unsaturated steroids†-Reference-Cited by-同舟云学术

An Unusual Ozonolysis of the Δ8(14)-unsaturated steroids†

Published:2002-08 Issue:8 Volume:2002 Page:392-394
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Krstić Natalija M.¹,Lorenc Ljubinka B.²,Pavlović Vladimir D.²,Kalvoda Jaroslav³,Tinant Bernard⁴,Declercq Jean-Paul⁴

Affiliation:

1. Center for Chemistry, ICTM, P. O. Box 473, YU-11001 Belgrade

2. Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, PO Box 158, YU-11001 Belgrade

3. Leimgrubenweg 21,CH-4102 Binningen, Switzerland

4. Laboratoire de Chimie Physique et de Cristalographie, Université Catholique de Louvain, 1 Place Louis Pasteur, B-1348 Louvain-la-Neuve, Belgium

Abstract

Ozonolysis of the Δ8(14)-unsaturated steroids 1a,b afforded, instead of the expected 8,14-dioxo-8,14-seco derivatives 2a,b two stereoisomeric Δ7-unsaturated ozonides 3a,b and 4a,b.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823402103172428

Reference7 articles.

1. MihailovićM. Lj., PavlovićV.D., Bondarenko-GheorghiuL.G., KrstićN.M., DabovićM.M., LorencLj. B., J. Serb. Chem. Soc., 1996, 61, 941.

2. RinikerB., ArigoniD., JegerO., Helv. Chim. Acta, 1954, 66, 546.

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