Ruthenium (VI) Catalysed Oxidation of Diols by Alkaline Hexacyanoferrate(III) ion – a Kinetic Study-Reference-Cited by-同舟云学术

Ruthenium (VI) Catalysed Oxidation of Diols by Alkaline Hexacyanoferrate(III) ion – a Kinetic Study

Published:2001-05 Issue:5 Volume:2001 Page:182-184
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Behari Kunj¹,Srivastava Roli¹,Veena ¹

Affiliation:

1. Department of Chemistry, University of Allahabad, Allahabad-211002, India

Abstract

The kinetics of Ru(VI) catalysed oxidation of 1,5 pentane diol; 1,6-hexane-diol, 1-pentanol and 1-hexanol by hexacyanoferrate (III) ion in an aqueous alkaline medium at constant ionic strength shows zero order dependence on hexacyanoferrate (III) and first order dependence on Ru(VI) and substrate. The result suggest that a complex is formed between Ru(VI) and diol, which slowly decomposes to give a reduced form of ruthenium, which is reoxidised to Ru(VI) in a fast step be alkaline hexacyanoferrate(III). A plausible reaction mechanism is proposed.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823401103169568

Reference12 articles.

1. CottonF.A., and WilkinsonG., Advanced Inorganic Chemistry, 3rd ed. Wiley Eastern Ltd., P. 1107, 1976, pp. 992–1009.

2. Kinetics and mechanisms of oxidation by metalions. Part XI(1). Kinetics of the osmium(VIII)-catalysed oxidation of glycols by alkaline hexacyanoferrate(III)

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