Reactions of Pyrylium Salts with Nucleophiles. Part 26.1 the Reaction with the Cyanide Anion Revisited-Reference-Cited by-同舟云学术

Reactions of Pyrylium Salts with Nucleophiles. Part 26.1 the Reaction with the Cyanide Anion Revisited

Published:2001-05 Issue:5 Volume:2001 Page:170-172
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Uncuta Cornelia¹,Tudose Adriana¹,Cãproiu Miron T.¹,Stavarache Carmen¹,Balaban Alexandru T.¹²

Affiliation:

1. Centre of Organic Chemistry “C.D. Nenitzescu”, 71141 Bucharest 15-254, Rumania

2. Texas A & M University at Galveston, Department of Marine Sciences, Galveston, TX 77553-1675, USA

Abstract

Reaction mechanisms are provided for the formation of diastereomeric 2,4-dialkyl-6-oxo-2,4-heptadienonitriles (including minor diastereoisomers observed for the first time) from 2,4,6-trialkylpyrylium salts and aqueous sodium cyanide.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823401103169522

Reference6 articles.

1. Reaction of pyrylium salts with nucleophiles. Part 25. Formation of pyridine-1-oxides, 2-isoxazolines and 1-pyrazoline-1-oxides

2. 699. Reaction of pyrylium salts with alkali cyanides

3. Configurations of Substituted 5-Cyanosorbic Acids. An Intramolecular Ritter Reaction

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