Aziridination of Methyl Long-chain Alkenoates Using Chloramine-T

Author:

Rauf Abdul1,Ahmad Shabana1

Affiliation:

1. Section of Oils and Fats, Department of Chemistry, Aligarh Muslim University, Aligarh-202002, India

Abstract

Methyl long-chain alkenoates on treatment with chloramine-T [N-chloro-N-sodio-p-toluenesulfonamide] resulted in the formation of the corresponding aziridines in moderate yields. The N-substituted aziridine derivatives based on methyl undec-10-enoate (1), methyl (Z)-octadec-9-enoate (3) and methyl (9Z,12R)-12-hydroxyoctadec-9-enoate (5) have been synthesised under mild reaction conditions. The products were characterised using micro-analytical and spectral data.

Publisher

SAGE Publications

Subject

General Chemistry

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