Rapid decomplexation of bis(thiosemicarbazonato)zinc(ll) complexes using citric acid-Reference-Cited by-同舟云学术

Rapid decomplexation of bis(thiosemicarbazonato)zinc(ll) complexes using citric acid

Published:2008-12 Issue:12 Volume:2008 Page:702-703
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Holland Jason P.¹²,Hickin Jennie A.¹,Grenville-Mathers Emma¹,Nguyen ThaoNguyen¹,Peach Josephine M.¹

Affiliation:

1. Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK

2. Memorial Sloan-Kettering Cancer Centre, 1275 York Avenue, New York, NY10021, USA

Abstract

Facile and quantitative dissociation of bis(thiosemicarbazonato)zinc(ll) complexes to give the corresponding neutral proligands in solution has been achieved by reaction with citric acid. This reaction provides an elegant solution to a problem encountered in the design, synthesis and purification of potential copper-based radiopharmaceuticals.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823408X380731

Reference13 articles.

1. Molecular imaging in drug discovery and development

2. Towards molecular imaging and treatment of disease with radionuclides: the role of inorganic chemistry

3. Radiohalogens for imaging and therapy

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