A Manganese-Based Coordination Polymer; Synthesis, Structure and Catalytic Activity-Reference-Cited by-同舟云学术

A Manganese-Based Coordination Polymer; Synthesis, Structure and Catalytic Activity

Published:2016-07 Issue:7 Volume:40 Page:422-427
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Alghool Samir¹²,Slebodnick Carla³,Khaled Khaled F.¹⁴

Affiliation:

1. Department of Chemistry, Faculty of Science, Taif University, 5700, Kingdom of Saudi Arabia

2. Department of Chemistry, Faculty of Science, Port Said University, Port Said, 42521, Egypt

3. Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, 24061, USA

4. Department of Chemistry, Faculty of Education, Ain Shams University, Cairo, Egypt

Abstract

Atwo-dimensional manganese(II)-based coordination polymer [Mn(L)4(CH3COO)2] [L=1,4-bis(1-imidazolyl)benzene] has been synthesised. Its X-ray structure revealed that the layers of the 2D structure are stacked together by two types of weak interactions extending to form a three-dimensional supramolecular structure. The thermal stability of this coordination polymer is described and the compound has been used as a heterogeneous catalyst in oxidation of cyclohexene to cyclohexene oxide. A density functional study of structural parameters, position of the HOMO and LUMO energies, electrophilicity and global hardness is reported.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751916X14655773247783

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5. Alkaline Post-Treatment of Cd(II)–Glutathione Coordination Polymers: Toward Green Synthesis of Water-Soluble and Cytocompatible CdS Quantum Dots with Tunable Optical Properties

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