Synthesis of Polynitrostilbenes from 2,4,6-Trinitro-M-Xylene and 2,4,6-Trinitrotoluene by a Microwave-Assisted Solvent Free Method-Reference-Cited by-同舟云学术

Synthesis of Polynitrostilbenes from 2,4,6-Trinitro-M-Xylene and 2,4,6-Trinitrotoluene by a Microwave-Assisted Solvent Free Method

Published:2014-04 Issue:4 Volume:38 Page:240-244
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Xu Junhui¹,Li Fangmei¹,Wei Jianping¹,Peng Xinhua¹

Affiliation:

1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P.R. China

Abstract

A microwave-assisted method for the synthesis of polynitrostilbenes involving the condensation of 2,4,6-trinitro- m-xylene and 2,4,6-trinitrotoluene with aryl aldehydes in the presence of piperidine and silica-gel is reported. Compared with conventional methods, a shorter reaction time is required and this method has a lower environmental impact. A mechanism for the reaction is also proposed and supported by UV-Vis absorption spectroscopy.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751914X13944453321075

Reference34 articles.

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2. Theoretical Investigation on Structures, Densities, Detonation Properties, and the Pyrolysis Mechanism of the Derivatives of HNS

3. Synthesis of Hexanitrostilbene (HNS) using a Kenics Static Mixer

4. Structure−Property Relationships for Two-Photon Absorbing Chromophores: Bis-Donor Diphenylpolyene and Bis(styryl)benzene Derivatives

5. Octupolar Crystals for Nonlinear Optics: 1,3,5-Trinitro-2,4,6-tris(styryl)benzene Derivatives

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