Synthesis of Novel Amide Molecular Tweezers under Solvent-Free Conditions Using Microwave Irradiation

Author:

Zeng Bitao1,Zhou Lijun1,Li Xiangbiao1,Zhao Xianming1,Zhao Zhigang2,Deng Mei1

Affiliation:

1. YiBin Vocational and Technical College, Yibin 644003, P. R. China

2. College of Chemistry and Environmental Protection Engineering, Southwest University for Nationalities, Chengdu 610041, P. R. China

Abstract

Twelve novel amide type molecular tweezer anion receptors based on phenyl-1, 4-dioxyacetic acid have been synthesised using microwave irradiation. Their structures were established by 1H NMR, IR, MS spectra and elemental analysis. Their binding properties were examined by UV-Vis spectra titration. The preliminary results indicate that these molecular tweezers show good recognition properties for Cl-, Br-, I-, CH3COO-.

Publisher

SAGE Publications

Subject

General Chemistry

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