Two Ways of Preparing Benzonitriles Using BrCCl3–PPh3 as the Reagent-Reference-Cited by-同舟云学术

Two Ways of Preparing Benzonitriles Using BrCCl3–PPh3 as the Reagent

Published:2014-02 Issue:2 Volume:38 Page:80-84
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Jasem Yosef Al¹,Barkhad Mohamed¹,Khazali Mona Al²,Butt Hifsa Pervez¹,El-Khwass Noha Ashraf³,AlAzani Mariam⁴,Hindawi Bassam al⁴,Thiemann Thies⁴

Affiliation:

1. Department of Chemical Engineering and, Faculty of Engineering, United Arab Emirates University, Al Ain, Abu Dhabi, UAE

2. Department of Petroleum Engineering, Faculty of Engineering, United Arab Emirates University, Al Ain, Abu Dhabi, UAE

3. Department of Chemistry, Cairo University, Cairo, Egypt

4. Department of Chemistry, Faculty of Science, United Arab Emirates University, Al Ain, Abu Dhabi, UAE

Abstract

Benzamides were converted into benzonitriles with BrCCl3–PPh3–Et3N in CH2Cl2 in an Appel-type reaction. Benzaldoximes could be transformed to benzonitriles under identical conditions. It was found that the reaction system BrCCl3–(2 equiv.)PPh3 was also suitable for these transformations with PPh3 replacing Et3N.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751914X13891131118347

Reference28 articles.

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