Eco-Friendly Mono-1,4-Hydrocyanation of Diarenyl Ketones Using Potassium Hexacyanoferrate(II) as a Cyanide Source-Reference-Cited by-同舟云学术

Eco-Friendly Mono-1,4-Hydrocyanation of Diarenyl Ketones Using Potassium Hexacyanoferrate(II) as a Cyanide Source

Published:2015-01 Issue:1 Volume:39 Page:44-47
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Hu Xiao-Ning¹,Liu Chen-Hui²,Li Zheng²

Affiliation:

1. Gansu Provincial Center for Disease Control and Prevention, Lanzhou, Gansu, 730000, P.R. China

2. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu, 730070, P.R. China

Abstract

A selective mono-1,4-hydrocyanation of 10 diarenyl ketones using potassium hexacyanoferrate(II) as an eco-friendly cyanide source, potassium hydroxide as a catalyst, and benzoyl chloride as a promoter has been achieved. This protocol has the advantages of a non-toxic cyanide source, a heavy metal-free catalyst, selectivity, very good yields and a simple work-up procedure.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751915X14197812950625

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