DBU-Promoted Cu(OAc)•H2O-Catalysed Coupling Reactions of Aryl Iodides and Sodium Azide-Reference-Cited by-同舟云学术

DBU-Promoted Cu(OAc)•H2O-Catalysed Coupling Reactions of Aryl Iodides and Sodium Azide

Published:2018-05-01 Issue:5 Volume:42 Page:247-250
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Jiang Yuqin¹,Suo Huajun¹,Zhao Yaru¹,Li Xiyong²,Sun Yamin²,Li Xingfeng¹,Dong Wenpei¹,Li Wei¹,Zhang Weiwei¹,Xu Guiqing¹

Affiliation:

1. Henan Engineering Laboratory of Chemical Pharmaceuticals & Biomedical Materials, Collaborative Innovation Centre of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, PR. China

2. Weihai Ocean Vocational College, Weihai, PR. China

Abstract

An efficient and simple protocol for the synthesis of aryl azides by the coupling of aryl iodides with sodium azide, in good to excellent yields in DMSO at 95 °C under catalysis by Cu(OAc)2-H2O and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), has been established. The optimised loadings of Cu(OAc)2-H2O and DBU were 10 mol% and 15 mol% respectively.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751918X15260507766192

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