Syntheses and Structures of Pseudo-Mauveine Picrate and 3-Phenylamino-5-(2-Methylphenyl)-7-Amino-8-Methylphenazinium Picrate Ethanol Mono-Solvate: The First Crystal Structures of a Mauveine Chromophore and a Synthetic Derivative-Reference-Cited by-同舟云学术

Syntheses and Structures of Pseudo-Mauveine Picrate and 3-Phenylamino-5-(2-Methylphenyl)-7-Amino-8-Methylphenazinium Picrate Ethanol Mono-Solvate: The First Crystal Structures of a Mauveine Chromophore and a Synthetic Derivative

Published:2015-12 Issue:12 Volume:39 Page:711-718
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Plater M. John¹,Harrison William T. A.¹,Rzepa Henry S.²

Affiliation:

1. Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, UK

2. Department of Chemistry, Imperial College, South Kensington Campus, London SW7 2AZ, UK

Abstract

Pseudo-mauveine picrate and a synthetic derivative of mauveine, 3-phenylamino-5-(2-methylphenyl)-7-amino-8-methylphenazinium picrate, have been prepared via their leuco-bases and their crystal structures determined. Time-dependent density functional theory gives a good match for the calculated and measured UV-Vis spectra.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751915X14474318419130

Reference32 articles.

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4. Does the Science Museum, London, have Perkin's Original Mauve Dye? A Critical Reassessment of a Chemical Icon

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