Oxidative Acetoxylactonisation of Alkenoic Acids Using H2O2 in Acetic Acid Catalysed by KI-Reference-Cited by-同舟云学术

Oxidative Acetoxylactonisation of Alkenoic Acids Using H2O2 in Acetic Acid Catalysed by KI

Published:2015-09 Issue:9 Volume:39 Page:518-520
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Zhou Zhong-Shi¹,He Xue-Han²

Affiliation:

1. College of Biological and Environmental Sciences, Zhejiang Shuren University, Hangzhou 310015, P. R. China

2. Zhejiang Institute of Geology and Mineral Resource Laboratory, Hangzhou 310007, P. R. China

Abstract

In the presence of a catalytic amount of KI in combination with H2O2, a convenient catalytic procedure has been developed for the direct preparation of acetoxylactones from alkenoic acids in acetic acid at room temperature which provides the corresponding cyclic products in good yields. This novel methodology mediated by an in situ generated hypervalent iodine intermediate extends the catalytic application of KI in organic synthesis.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751915X14399788140213

Reference20 articles.

1. Organic Polyvalent Iodine Compounds

2. Recent Developments in the Chemistry of Polyvalent Iodine Compounds

3. Solvolysis of Vinyl Iodonium Salts. New Insights into Vinyl Cation Intermediates

4. Cyclic diaryliodonium ions: old mysteries solved and new applications envisaged

5. Iodobenzene-Catalyzed α-Acetoxylation of Ketones. In Situ Generation of Hypervalent (Diacyloxyiodo)benzenes Using m-Chloroperbenzoic Acid

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1. ChemInform Abstract: Oxidative Acetoxylactonisation of Alkenoic Acids Using H2O2in Acetic Acid Catalyzed by KI.;ChemInform;2016-03