A Doubly End-On Azido-Bridged Trinuclear Cu(II) Complex: Synthesis, Spectral and DFT Functional Studies-Reference-Cited by-同舟云学术

A Doubly End-On Azido-Bridged Trinuclear Cu(II) Complex: Synthesis, Spectral and DFT Functional Studies

Published:2011-03 Issue:3 Volume:35 Page:140-143
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Datta Amitabha¹,Das Kuheli²,Huang Wen-Yen¹,Huang Jui-Hsien¹,Liao Fu-Xing¹,Hu Ching-Han¹

Affiliation:

1. Department of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan

2. Department of Chemistry, National Chung-Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan

Abstract

A trinuclear, doubly azido-bridged Cu(II) complex, [Cu1.50(L)(N3)3(CH3OH)]2, (LH = [(CH3)2NCH2CH2N=CHC6H3(OH) (OMe)]), has been synthesised and fully characterised by elemental analyses, IR, UV-Vis, EPR and DFT studies. Its single crystal X-ray structure reveals that adjacent CuII ions are linked by double end-on azido-bridges; thus the full molecule is generated by the site symmetry of a crystallographic two-fold rotation axis.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751911X12972790588178

Reference47 articles.

1. Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes

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