Synthesis and Crystal Structures of Some New 2-(Diphenylamino)-4,5-Disubstituted Thiazole Derivatives

Author:

Heydari Reza1,Shahrekipour Fahimeh1,Graiff Claudia2,Tahamipour Batool3

Affiliation:

1. Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, PO Box 98135-674, Zahedan, Iran

2. Dipartimento di Chimica, Universitá di Parma, Viale delle Scienze 17/A Campus Universitario 43100, Parma, Italy

3. Farhangian University of Kerman, Kerman, Iran

Abstract

The reactions of diphenylamine and benzoyl isothiocyanates with phenacyl bromide or methyl 2-bromoacetate in the presence of triethylamine yield 2,4,5-trisubstituted thiazole derivatives. The molecular structures of [2-(diphenylamino)-4-phenylthiazol-5-yl]( o-tolyl) methanone and methyl 4-(4-chlorophenyl)-2-(diphenylamino)thiazole-5-carboxylate have been fully determined by means of single crystal X-ray diffraction methods.

Publisher

SAGE Publications

Subject

General Chemistry

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