Ultrasound Assisted Ring-Opening Reaction of Epoxides with 1,2-DiphenylDiselenide-Reference-Cited by-同舟云学术

Ultrasound Assisted Ring-Opening Reaction of Epoxides with 1,2-DiphenylDiselenide

Published:2011-09 Issue:9 Volume:35 Page:522-524
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Cheng Tianxing¹,Zheng Xiangyong²,Ke Qiang²

Affiliation:

1. The Key Laboratory of Leather Engineering of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325027, P. R. China

2. College of Life and Environmental Sciences, Wenzhou University, Wenzhou 325035, P. R. China

Abstract

Ultrasound assisted ring-opening of epoxides with 1,2-diphenyldiselenide in PEG-400/H2O in the presence of sodium dithionite has been developed, affording β-hydroxy selenides with high regioselectivity in good to excellent yields. Importantly, the present protocol is very practical and highly efficient since it does not require the use of expensive and unpleasant smelly reagent.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751911X13149579868111

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5. A rapid and high-yielding synthesis of β-hydroxyselenides by regio- and stereoselective ring-opening of epoxides with benzeneselenol using ammonium-12-molybdophosphate

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