Preparation of Novel Molecular Tweezers based on 3,6-O-(2-acylhydrazinocarbonyl) Esters of Hyodeoxycholic acid using Microwave Irradiation

Author:

Li Xiaorui1,Qiu Liying1,Mei Qinggang1,Bi Qingwei1,Zhao Zhigang1

Affiliation:

1. College of Chemistry and Environmental Protection Engineering, Southwest University for Nationalities, Chengdu 610041, P. R. China

Abstract

Ten novel molecular tweezers based on the 3,6- O-(2-acylhydrazinocarbonyl) esters of hyodeoxycholic acid have been synthesised using microwave irradiation. Their structures were established by 1H NMR, IR, MS spectra and elemental analysis. Their binding properties were examined by UV-Vis spectra titration. The preliminary results indicate that these molecular tweezers show good recognition properties for Cl-, Br-, I-.

Publisher

SAGE Publications

Subject

General Chemistry

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