Reactivity of Neodymium and Samarium Nitrides-Reference-Cited by-同舟云学术

Reactivity of Neodymium and Samarium Nitrides

Published:2017-02 Issue:2 Volume:41 Page:82-84
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Kuzyaev Dmitry M.¹,Maleev Alexander A.¹,Kulikova Tatyana I.¹,Vorozhtsov Dmitry L.²,Bochkarev Mikhail N.¹²

Affiliation:

1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Tropinin str. 49, 603950 Nizhny Novgorod, Russian Federation

2. Nizhny Novgorod N. I. Lobachevsky State University, Gagarin Avenue 23, 603950 Nizhny Novgorod, Russian Federation

Abstract

The reaction of NdN and SmN with iodine gave the iodide-nitrides (NdI2)3N(DME)4 and (SmI)3N2(THF)2, which are inert towards sulfur, in contrast to the neodymium and dysprosium iodide-nitrides prepared by the reaction of LnI2 with N2. Reaction of NdN and SmN with C6F5OH and CpH gave the organolanthanide derivatives Ln(C5F5O)3(THF)n (Ln = Nd or Sm) and Cp3Sm with moderate and low yields, respectively. Phenylacetylene and styrene do not react with SmN.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/174751917X14839766277332

Reference24 articles.

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3. Molecular and Crystal Structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and Related Compounds

4. N-Metallation of MS2N2rings. X-ray crystal structures of [(η5-C5Me5)Ir(S2N2)Au(PPh3)][ClO4], [{(η5-C5Me5)Ir(S2N2)Au}2(μ2-dppm)][ClO4]2and [Au(dppeS-P)Cl]2

5. Five-Membered Arsenic−Sulfur−Nitrogen Heterocycles, RAs(S2N2) (R = Me, Et, iPr, tBu, Ph, Mes)

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